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Abstract

The redox properties of metallic nanoparticles are discussed, in particular the relationships between excess charge, size and the Fermi level of the electrons. The redox potentials are derived using simple electrostatic models to provide a straightforward understanding of the basic phenomena. The different techniques used to measure the variation of Fermi level are presented. Finally, redox aspects of processes such as toxicity, electrochromicity and surface plasmon spectroscopy are discussed.

Keywords

Nanoscopic scaleNanoparticleMetalMaterials scienceNanotechnologyFermi levelFermi Gamma-ray Space TelescopeChemical physicsCondensed matter physicsChemistryPhysicsMetallurgyElectronQuantum mechanics

Identifiers

Journal
Chemical Science
Year
2015