Preparation of g-C3N4/Graphene Composite for Detecting NO2 at Room Temperature

Abstract

Graphitic carbon nitride (g-C₃N₄) nanosheets were exfoliated from bulk g-C₃N₄ and utilized to improve the sensing performance of a pure graphene sensor for the first time. The role of hydrochloric acid treatment on the exfoliation result was carefully examined. The exfoliated products were characterized by X-ray diffraction (XRD) patterns, scanning electron microscopy (SEM), atomic force microscopy (AFM), and UV-Vis spectroscopy. The exfoliated g-C₃N₄ nanosheets exhibited a uniform thickness of about 3-5 nm and a lateral size of about 1-2 µm. A g-C₃N₄/graphene nanocomposite was prepared via a self-assembly process and was demonstrated to be a promising sensing material for detecting nitrogen dioxide gas at room temperature. The nanocomposite sensor exhibited better recovery as well as two-times the response compared to pure graphene sensor. The detailed sensing mechanism was then proposed.

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Identifiers

DOI

10.3390/nano7010012

PubMed

28336846

Journal

Nanomaterials

Year

2017