Proficient Sanitary Wastewater Treatment in Laboratory and Field-Scale Microbial Fuel Cell with Anti-Biofouling Cu₀.₅Mn₀.₅Fe₂O₄ as Cathode Catalyst

Abstract

For successful field-scale application of microbial fuel cell (MFC), the power recovery from field-scale MFC needs to be improved considerably with simultaneous reduction in its fabrication cost. These problems can be addressed by applying low-cost and efficient cathode catalyst in MFCs. In this regard, Cu 0.5 Mn 0.5 Fe 2 O 4 (CuMnFe) was synthesized and applied as cathode catalyst in lab and field-scale MFCs with capacity of 150 ml and 25 l, respectively. Lab-scale MFC having CuMnFe as cathode catalyst demonstrated power density of 176.0 ± 8.2 mW m −2 , which was competitive with MFC having Pt as cathode catalyst (183.0 ± 12.6 mW m −2 ) and it was about seven times higher than control MFC (25.5 ± 4.5 mW m −2 ) having no catalyst. Application of CuMnFe as cathode catalyst in field-scale MFC produced power density of 7.74 mW m −2 , which was three-times higher than the power produced by the field-scale MFC operated without any cathode catalyst (2.58 mW m −2 ). The cathode catalyst CuMnFe also demonstrated excellent anti-biofouling properties, which in turn improved the power production of field-scale MFC. Therefore, low-cost CuMnFe can be anticipated as an efficacious cathode catalyst for application in MFCs that would produce long term stable higher power, while offering simultaneous treatment to wastewater.

Key findings

• ▸Lab-scale MFC with CuMnFe cathode catalyst achieved power density of 176.0 ± 8.2 mW m⁻², comparable to Pt catalyst (183.0 ± 12.6 mW m⁻²) and 7 times higher than control MFC.
• ▸Field-scale MFC with CuMnFe cathode catalyst produced power density of 7.74 mW m⁻², 3 times higher than field-scale MFC without cathode catalyst.
• ▸CuMnFe cathode catalyst demonstrated anti-biofouling properties.

Keywords

Identifiers

DOI

10.1149/1945-7111/abfe77

Journal

Journal of The Electrochemical Society

Year

2021