Molten carbonate fuel cell stack performance with gas recycling

Abstract

Abstract The molten carbonate fuel cell (MCFC) power plant is expected to be one of the most promising future power generation systems for the electric utilities because of its high efficiency, environmental suitability and capability of using coal as fuel. To obtain such attractive performance, it is necessary for the plant to adopt the gas‐recycling operation system. The authors tested a 6‐kW class MCFC stack with three types of gas recyclings, i.e., cathode, anode and carbon dioxide ones, including pressurized conditions. This paper describes the test results and the effects of the gas‐recycling operations. Cathode gas recycling is proved to be able to control the stack temperature and give the flexibility for setting oxygen utilization. Anode gas recycling is proved to be able to suppress the methane formation and decrease the deviation of the stacked cell voltages. Including the starting‐up process, it is proved that the electricity can be generated from the stack without supplying carbon dioxide from outside the system by carbon dioxide gas recycling. In such a process using a burner for carbon dioxide gas recycling, burner temperature must be controlled to a certain value. It is important to adjust the fuel supplying rate, load current and cathode gas‐recycling ratio to each other. At the load change process, constant gas utilization operation is not effective in changing the burner temperature.

Key findings

• ▸Cathode gas recycling controlled the stack temperature and gave flexibility for setting oxygen utilization.
• ▸Anode gas recycling suppressed methane formation and decreased deviation of stacked cell voltages.
• ▸Carbon dioxide gas recycling allowed electricity generation without external carbon dioxide supply.

Keywords

Identifiers

DOI

10.1002/eej.4391140604

Journal

Electrical Engineering in Japan

Year

1993