Modification of Graphite Sheet Anode with Iron (II, III) Oxide-Carbon Dots for Enhancing the Performance of Microbial Fuel Cell

Abstract

The present study explores the use of carbon dots coated with Iron (II, III) oxide (Fe3O4) for its application as an anode in microbial fuel cells (MFC). Fe3O4@PSA-C was synthesized using a hydrothermal-assisted probe sonication method. Nanoparticles were characterized with XRD, SEM, FTIR, and RAMAN Spectroscopy. Different concentrations of Fe3O4- carbon dots (0.25, 0.5, 0.75, and 1 mg/cm²) were coated onto the graphite sheets (Fe3O4@PSA-C), and their performance in MFC was evaluated. Cyclic voltammetry (CV) of Fe3O4@PSA-C (1 mg/cm²) modified anode indicated oxidation peaks at −0.26 mV and +0.16 mV, respectively, with peak currents of 7.7 mA and 8.1 mA. The fluxes of these anodes were much higher than those of other low-concentration Fe3O4@PSA-C modified anodes and the bare graphite sheet anode. The maximum power density (Pmax) was observed in MFC with a 1 mg/cm² concentration of Fe3O4@PSA-C was 440.01 mW/m², 1.54 times higher than MFCs using bare graphite sheet anode (285.01 mW/m²). The elevated interaction area of carbon dots permits pervasive Fe3O4 crystallization providing enhanced cell attachment capability of the anode, boosting the biocompatibility of Fe3O4@PSA-C. This significantly improved the performance of the MFC, making Fe3O4@PSA-C modified graphite sheets a good choice as an anode for its application in MFC.

Key findings

• ▸Modification of graphite sheet anodes with Fe3O4@PSA-C increases flux and peak currents in cyclic voltammetry.
• ▸The maximum power density of MFCs using Fe3O4@PSA-C modified anodes is 440.01 mW/m², 1.54 times higher than bare graphite sheet anodes.
• ▸The elevated interaction area of carbon dots allows for enhanced Fe3O4 crystallization and cell attachment, boosting biocompatibility.

Keywords

Identifiers

DOI

10.3390/catal12091040

Journal

Catalysts

Year

2022