Study on Purging Strategy of Polymer Electrolyte Membrane Fuel Cell under Different Operation Conditions

Abstract

The commercial proton exchange membrane fuel cell (PEMFC) system needs to be equipped with the capacity to survive a harsh environment, including sub-freezing temperatures. The cold start of PEMFC brings about great technical challenges, mainly due to the ice blockage in the components, which seriously hinders the multi physical transmission process. A multiscale, two-dimensional model was established to explore the gas purging in PEMFC under different electrochemical reaction intensities. The results indicate that the optimal case is obtained by B3-1 with a power density of 0.796 W cm⁻², and the power density increases first and then decreases, followed by stoichiometric flow ratio (ξ) changes. It is worth noting that the water mole fraction in the PEM is closely related to the water concentration gradient. However, the differences in the initial water distribution in porous media have little bearing on the condensed water in the gas channel, and the liquid water in the gas diffusion layer (GDL) is preferably carried away ahead of other porous parts. The results also show that the increase in the purge speed and temperature can remove the excess water on GDL and the catalytic layer in a short time. For a nitrogen-based purge, the operating condition in case B3-1 is shown as the best strategy based on the output performance and economic analysis during the shutdown and purge process.

Key findings

• ▸The power density increases first and then decreases, followed by stoichiometric flow ratio (ξ) changes.
• ▸The water mole fraction in the PEM is closely related to the water concentration gradient.
• ▸The increase in the purge speed and temperature can remove the excess water on GDL and the cataly

Keywords

Identifiers

DOI

10.3390/pr11010290

Journal

Processes

Year

2023