Advances in Fuel Cell Performance Using Simulation Analysis in Toshiba Energy Systems & Solutions Corporation

Abstract

Toshiba’s Stationary Fuel Cell System Toshiba Energy Systems & Solutions Corporation is developing hydrogen solution, which is a key technology to achieve carbon neutral. Now we are manufacturing the pure hydrogen fuel cell systems for stationary application. This fuel cell systems have some models up to 100kW, and in order to provide the larger electricity than 100kW, the 100kW system can be operated connecting several units up to 1MW. Toshiba's fuel cell systems have been achieved stable, long-term operation, high durability, and high energy efficiency. These features are realized by internal water management cell stack conflagration using porous carbon bi-polar plates. The porous bi-polar plates can humidify reactant gases supplied as vapor from the surface of the porous bi-polar plates and removes produced water through the porous bi-polar plates by the pressure difference between the reactant gases and the coolant water. This technology realizes ideal conditions in terms of water activity entire active area, suppressing overpotentials due to flooding and temperature and water activity distribution. This technology enables stable continuous operation up to 1 week and design life of 80,000 hours confirmed by demonstration tests, which is one of the highest in the world. Recent trends in fuel cell development include the growing expectation and demand for higher capacity and long durability fuel cell systems for stationary applications such as carbon neutral complexes and data centers, etc. In addition, demand for high power density fuel cell systems for large commercial mobility vehicles, such as buses and trucks, is also increasing. In order to meet this demand, Toshiba is developing elemental technologies for higher performance fuel cells. Development of advanced high performance fuel cells In order to improve cell performance, it is necessary to reduce ohmic, activation, and diffusion polarizations. Among these three overpotentials, a reduction of diffusion polarization is particularly important to achieve operation up to the high current density. To reduce diffusion polarization, the flow field of bi-polar plates must be designed to improve the limiting current density by efficient gas supply to the catalyst layer and to reduce mass transport resistance in the gas diffusion layer and catalyst layer. Toshiba has focused on reducing this diffusion polarization and is working on the flow field design using numerical simulation. As an example, Toshiba has developed the advanced numerical simulation by introducing mass transfer models of water evaporation and water absorption on the surface of a porous bi-polar plates into a commercially available electrochemical reaction and thermal fluidics 3D simulator. This porous bi-polar plates model was then used to perform parametric study of the flow field design, and determine parameters in terms of gas diffusivity, electrical resistance, and temperature and humidity distribution. And then, the advanced cell that incorporating designed bi-polar plates, thinner components, and a new catalyst was fabricated and evaluated. Figure 1 shows comparison of cell performance between conventional and advanced cells. The limiting current density of advanced cell is 3.6 times larger than that of conventional cell due to simulation-based flow field design and optimization of operating pressure. The application of these development items and optimization of operating conditions reduced each polarization and achieved a current density twice that of conventional cell. In the future, we aim to achieve even higher performance by improving catalytic activity and reducing cell resistance through thinner components. Figure 1

Key findings

• ▸The fuel cell system has achieved stable, long-term operation and high durability.
• ▸The system has high energy efficiency due to internal water management and porous carbon bipolar plates.
• ▸The porous bipolar plates can humidify reactant gases and remove produced water, suppressing overpotentials.

Keywords

Identifiers

DOI

10.1149/ma2024-02463275mtgabs

Journal

ECS Meeting Abstracts

Year

2024