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The Active Hydrogen Electrochemically or Thermally Generated on Pd/H3PO4/Pd Catalysts
Kiyoshi Otsuka, Ichiro Yamanaka
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100% confidenceMES research in electrode, bacteria. Abstract Hydrogenation of 2-propanol into propane wa...
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Abstract
Abstract Hydrogenation of 2-propanol into propane was caused by the hydrogen atoms electrochemically generated on Pd-black of the electrocatalytic cell Pd/H3PO4/Pd. The reaction was also caused by the hydrogen generated through spillover and reverse spillover between Pd and H3PO4. Under closed circuit conditions, the latter hydrogenation over the anode Pd was retarded because of the inhibition of the reverse spillover.
Keywords
CatalysisHydrogenPalladiumInorganic chemistryChemical engineering
Identifiers
- Journal
- Chemistry Letters
- Year
- 1987