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Hydrochar-doping improves the performance of carbon felt as an anodic electrode in microbial fuel cells, with activated hydrochar achieving 30% higher power and current density compared to non-doped or non-activated hydrochar.

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System
MFC

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Abstract

In this study, the feasibility of using hydrochars as anodic doping materials in microbial fuel cells (MFCs) was investigated. The feedstock used for hydrochar synthesis was metal-polluted plant biomass from an abandoned mining site. The hydrochar obtained was activated by pyrolysis at 500 °C in N 2 atmosphere. Under steady state conditions, the current exerted by the MFCs, as well as the cyclic voltammetry and polarization curves, showed that the activated hydrochar-doped anodes exhibited the best performance in terms of power and current density generation, 0.055 mW/cm 2 and 0.15 mA/cm 2 , respectively. These values were approximately 30% higher than those achieved with non-doped or doped with non-activated hydrochar anodes which can be explained by the highly graphitic carbonaceous structures obtained during the hydrochar activation that reduced the internal resistance of the system. These results suggest that the activated hydrochar materials could significantly enhance the electrochemical performance of bioelectrochemical systems. Moreover, this integration will not only enhance the energy generated by MFCs, but also valorize metal polluted plant biomass within the frame of the circular economy.

Keywords

Electrochemical performanceElectrodesHydrocharHydrothermal carbonizationMicrobial fuel cell

Identifiers

PubMed
38653895
Journal
Environmental science and pollution research international
Year
2025