Natural Wolframite Used as Cathode Photocatalyst for Improving the Performance of Microbial Fuel Cells

Abstract

Developing simple and cheap electrocatalysts or photocatalysts for cathodes to increase the oxygen reduction process is a key factor for better utilization of microbial fuel cells (MFCs). Here, we report the investigation of natural wolframite employed as a low-cost cathode photocatalyst to improve the performance of MFCs. The semiconducting wolframite was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Raman spectroscopy. The band gap and photo respond activities were determined by UV-vis spectroscopy and linear sweep voltammetry (LSV), respectively. Compared with the normal graphite cathode, when MFCs were equipped with a wolframite-coated cathode, the maximum power density was increased from 41.47 mW·m⁻² to 95.51 mW·m⁻². Notably, the maximum power density further improved to 135.57 mW·m⁻² under light irradiation, which was 2.4 times higher than with a graphite cathode. Our research demonstrated that natural wolframite, a low-cost and abundant natural semiconducting mineral, showed promise as an effective photocathode catalyst which has great potential applications related to utilizing natural minerals in MFCs and for environmental remediation by MFCs in the future.

Key findings

• ▸Natural wolframite increased maximum power density from 41.47 mW·m⁻² to 95.51 mW·m⁻² compared to a graphite cathode.
• ▸Maximum power density further improved to 135.57 mW·m⁻² under light irradiation, a 2.4-fold increase over graphite.
• ▸Wolframite-coated cathodes showed promise as effective photocathode catalysts for MFCs.

Keywords

Identifiers

DOI

10.3390/app8122504

Journal

Applied Sciences

Year

2018