Bio-Waste Derived Honeycomb Structured Activated Carbons as Anode Materials for Lead-Carbon Hybrid Ultracapacitors

Abstract

Lead-carbon hybrid ultracapacitors (Pb-C HUC) are the solution to the sulfation issue of lead-acid batteries. The Pb-C HUCs are of much interest due to the aqueous system with longer cycle life and higher power density. Here, honeycomb structured porous activated carbons with 1790 m 2 g −1 of surface area were synthesized from Carica papaya biowaste by chemical treatment followed by carbonization at 800 °C (PAC-800). PAC-800 composite electrode delivers a specific capacitance of 250 F g −1 at 1 Ag −1 and has 10000 stable cycle life in 4.5 M H 2 SO 4 . Further, a kinetic study of the PAC-800 electrode illustrates that at 2 mV s −1 , they show 61% of capacitive and 39% of pseudocapacitive charge storage. Pb-C HUCs fabricated using in situ activated PbO 2 sheet as cathode and PAC-800 composite electrode as anode delivers 390 F g −1 at 1 A g −1 and have 93% capacitance retention over 15000 cycles at 5 A g −1 . Further, the current Pb-C HUC results are compared with commercially available high surface area (2484 m 2 g −1 ) carbons based Pb-C HUCs. This work illustrates an easy, scalable synthesis root for biowaste carbons and their electrochemical performance in Pb-C HUCs, which is on par with commercial high surface area carbons.

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Identifiers

DOI

10.1149/1945-7111/ac8eda

Journal

Journal of The Electrochemical Society

Year

2022