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The paper reviews MOF-based catalysis, discussing various approaches to catalysis within metal-organic frameworks.

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Abstract

A critical review of the emerging field of MOF-based catalysis is presented. Discussed are examples of: (a) opportunistic catalysis with metal nodes, (b) designed catalysis with framework nodes, (c) catalysis by homogeneous catalysts incorporated as framework struts, (d) catalysis by MOF-encapsulated molecular species, (e) catalysis by metal-free organic struts or cavity modifiers, and (f) catalysis by MOF-encapsulated clusters (66 references).

Keywords

CatalysisMetal-organic frameworkHomogeneousSynergistic catalysisHomogeneous catalysisHeterogeneous catalysis

Identifiers

DOI
10.1039/b807080f
Journal
Chemical Society Reviews
Year
2009